Chlorido(chlorodiphenylphosphine-κP)(diphenylpiperidinophosphine-κP)(η5-pentamethylcyclopentadienyl)ruthenium(II)
نویسندگان
چکیده
The title compound, [Ru(C(10)H(15))Cl(C(12)H(10)ClP)(C(17)H(20)NP)], is a half-sandwich complex of Ru(II) with the chloro-diphenyl-phosphine ligand formed from the diphenyl-piperidinophosphine and chlorine of the precursor complex [Ru(η(5)-C(5)Me(5))(κ(1)P-Ph(2)PNC(5)H(10))Cl(2)] by an unexpected reaction with NaBH(4). The complex has a three-legged piano-stool geometry, with Ru-P bond lengths of 2.2598 (5) Å for the chloro-phosphine and 2.3303 (5) Å for the amino-phosphine.
منابع مشابه
Chlorido[1-diphenylphosphanyl-3-(phenylsulfanyl)propane-κ2 P,S](η5-pentamethylcyclopentadienyl)iridium(III) chloride monohydrate
The crystal structure of the title compound, [Ir(C(10)H(15))Cl(C(21)H(21)PS)]Cl·H(2)O, consists of discrete [Ir(η(5)-C(5)Me(5))Cl{Ph(2)P(CH(2))(3)SPh-κP,κS}](+) cations, chloride anions and water mol-ecules. The Ir(III) atom is coordinated by an η(5)-C(5)Me(5) ligand, a chloride and a Ph(2)P(CH(2))(3)SPh-κP,κS ligand, leading to a three-legged piano-stool geometry. In the crystal, two water mol...
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The author list in the paper by Tong, Hung, Wang, Lin & Lo [Acta Cryst. (2009), E65, m438] is corrected.[This corrects the article DOI: 10.1107/S1600536809010265.].
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